Wednesday, December 19, 2012

Iron to Wire? Some considerations on materials.

 As frequent readers know - I do spend (too much?) time every day on detailed answers / comments to various questions that come into me via e-mail. These pieces would be 'lost' if only sent to one respondent, and so often are modified to become the meat for postings here....

On 17/12/12 1:00 PM, Stephen **** wrote:
...
My interest is in replicating historical wire - iron, steel, and brass - for musical instruments. The research is done as part of my work at (named University), but it's also practical in the sense of replicating it for a niche market. I'm already selling iron wire and investigating the other materials. As you can imagine, production economics is a nasty constraint. A big problem is getting from cast ingots to rod stock. Historically this would have been hot worked by powered tilt hammer, which is probably not economically viable nowadays even with access to appropriate equipment. The wire drawing operations push up the $/kg production cost of the finished wire so there isn't a lot of $ room in the heavy stage production of the rods. I came across your 'bloom 2 bar' project and wondered what practical solution you might have come up with for converting your bloom iron to bar.
A couple of things in your message:

"I'm already selling *iron* wire"
Since you are being specific, I take it what you really mean is a modern Bessemer produced low carbon content *steel* wire. 'Black Iron' fencing wire one possibility. Getting 'soft iron rivet' material is another. A third would be the use of 'Electric' or 'French' iron. (All these are NOT the same as historic wrought iron material.)
I drone on about this endlessly, but actual *bloomery* iron / *wrought* iron is no longer available in commercial production. I have seen some hints that smaller amounts might be under production in China - but only as a material for specialized blade replicas. Other than that, these ancient / historical methods are only employed in very small scale - by people like me
(demented wackos) .

"historically hot worked by tilt hammer"
Most modern day professional artisan blacksmiths will have some kind of power assisted hammer in their shop. These fall into mechanical or air driven types. This does allow for the working of more massive bars.
I have both a 30 ton hydraulic press, designed for initial bloom compaction, and a 50 lb throw air hammer in my own shop for example.
The problem is actually on the other side - small diameter bar into wire. Few have the special equipment (or specific skills or experience) for drawing wire. I certainly have never done this.

"selling iron, steel and brass wire"
Wire of various copper alloys (tin and zinc alloys) is certainly available. A problem might be getting small enough order quantities against your business volumes.
*Steel* - as in modern produced simple iron plus carbon alloys will also be available in almost any combination you might require. I expect there that the purchase sizes may be much smaller, although some hunting might be required to find just what modern business might sell small amounts of exactly the specific alloy you might want. (Auto repair for example)

As you certainly are aware, actual *bloomery / wrought* irons are distinctive in their physical composition (this separate from alloy composition). They will contain some level of hard glassy slag, if only at a microscopic level. This will effect their mechanical properties, I suspect in ways that might be critical to your application as drawn wire in musical instruments.
These materials are also not consistent through their volume - the way modern industrial steel alloys are. This likely presents a huge problem for your specific application.

This all represents a major terminology problem - one that is not dealt with effectively (to my observation) by museums and academic researchers. "Steel" is used generically for any iron plus carbon alloy - reguardless of its method of production or physical structure.
In working from a natural iron oxide source ore into a working metal bar, there are effectively *three*  different factors that might effect the characteristics of the end product.

1) How the iron oxide was physically reduced down to a metallic iron mass.
This is the type and individual design of the furnace, related to the method of production, modified by the specific ore itself. Experience and skill of the iron master comes into play here.

2) How that iron mass is physically manipulated in secondary processing after it has been created.

3) The actual alloy chemistry of the starting mass, as potentially modified by the secondary processing. Primarily the single largest variation comes through changes in the carbon component of the metal.

In short, depending on the starting iron ore, different furnaces may produce different products, both physically and chemically. How the iron master controls the iron smelting sequence can also modify both.
It is quite possible to get radically different carbon contents from the same ore (even in the same furnace).
The resulting mass can then be manipulated in different ways during the 'bloom to bar' process. This may change physical structure and carbon content.
Carbon can both be removed, but also added during secondary or tertiary forging processes.

Often historic bloomery iron materials were effectively impregnated with additional carbon through surface diffusion. You can see how this would produce a material with a layered texture, including some degree of slag filaments, which then varied in carbon content from a higher C exterior fading to a low C interior. Compressed into a wire, this might seriously effect the performance of that wire musically.


I refer you to Lee Sauder (www.leesauder.com). A close friend and fellow researcher - and easily the most skilled bloomery iron master in North America. Lee also does sell both raw bloom sections and blooms worked to billets.

Sunday, December 16, 2012

IS there Iron? - Part 3

As a refresher, this is a continuation of the series report on field walking in November. Generally not a bad time for this, the vegetation has died back, the bugs are gone, the water levels often lower. This year (despite claims by fools in America) the impact of global climate change (and Canadian warming) was clear. Mid November and still no snow!

IS there Iron - Part 1
IS there Iron - Part 2
North Erie Shore - Bog Iron

Take a look at the map of the region around Wareham again:

10 km range circles
Location 1, Bellfountain, was discussed in Part 2.

A couple of days later I had occasion to run up to Collingwood (look NE of Wareham, along Georgian Bay). On the way back I ran on a rough diagonal line back to Wareham, more or less along County Road 32. This lays along a valley cut into the edge of Blue Mountain. Note that Blue 'Mountain' is really the slope of the edge of the massive limestone block of the Niagara Escarpment - not a true 'mountain'. 
I did see at least one spot that looked like it was at least worth a closer examination when seen from the road. This was a very sharp cut of a stream bed that exposed the underlaying rock. Massive problem however - hunting season! It was late afternoon, and the road was dotted with trucks unloading men in orange jackets with rifles. (I was furious at this, the area was well sign posted as being provincial park land - 'No Hunting' signs all over.) I most certainly was NOT going to chance leaving the roadway!

Location 2 - Chepstow

A week later, I paid a visit to my close friend David Robertson, who had seen potential signs of iron south of his home / shop near Chepstow (look to the far west side of the map).


The spot was a rock cut into a shallow valley, which had a swampy bottom with a small stream running through it. David's thought was that this bottom land might contain bog iron ore, deposited from what he thought looked like iron contained in the surrounding rock.
On closer examination, the staining on the limestone was in fact a reddish yellow clay deposit, washing out of the stone. Although the colour was likely do to traces of iron oxide, there was only minimal amounts of iron present. Certainly not enough to constitute a useful ore.
(And truthfully, it was absolutely pissing down a hard cold rain - we were soaked to the skin in the five minutes at the rock cut alone. Retreat for hot wiskeys was called for!)

Location 3 - East Owen Sound.

Another place where the parent rock of the Escarpment is cut through is at Owen Sound, about 45 minutes drive north of Wareham. About mid November, I had to run up that way for steel supplies. I drove over to the east of town, where again the rock is exposed. I ended up not getting out of the truck for a closer look. The stone was very similar in appearance to that seen in the image above - a light yellow porous limestone.

Location 4 - East Markdale

On the way back home, I travelled down via a series of dirt roads more or less straight south from the Owen Sound area. The table of the Dundalk Plateau is cut by a number of deep river valleys (originally glaciers) through that area. The Beaver Valley is the one just to the north of Wareham, running SW to NE, from roughly Flesherton towards Thornbury on the map.

(Sorry about the image quality on these next)

Limestone at the edge of the valley cut
Tumbled blocks at the foot of the cliff
As you can see from the image, the stone here is a more solid, hard, dark to medium grey limestone. There was no evidence of iron staining at all. Although the heavily moss covered rocks were quite magical in appearance, there is no iron present.

Friday, December 07, 2012

December 7, 1941


Photo #: 80-G-19942

Pearl Harbor Attack, 7 December 1941


USS Arizona (BB-39) sunk and burning furiously, 7 December 1941. Her forward magazines had exploded when she was hit by a Japanese bomb.
At left, men on the stern of USS Tennessee (BB-43) are playing fire hoses on the water to force burning oil away from their ship

Official U.S. Navy Photograph, National Archives collection
 Image loading from :

Pearl Harbor Raid, 7 December 1941
Overview and Special Image Selection

Sauder's Standard Test

The following was posted by Lee Sauder on to Facebook. As frequent readers here know, Lee is largely responsible for the Early Iron movement in the USA (and a close friend). I have stolen his posting to the 'Iron Smelters of the World' Facebook group to help spread his suggestion.
 
 
 Since Mark (Green) brought up the twist testing, I thought I'd you tell my way of doing it. I've been testing blooms this way for a couple of years- the nice thing about it is that you not only get the subjective feeling of the iron, (which is easily confused or forgotten), but there's an easily quantifiable record as well-- how many twists it takes before it fails. I've found this very helpful to understand what I've done without expensive chemical analysis, which isn't really as meaningful as how tough the iron really is. I like do do this with the bloom hot right out of the smelt, so the test is still connected with the memory of the smelt.
Sectioned bloom and ancony with twist test.
If we all did this in a similar way, we'd have a better way to compare and communicate our results. Here's my way- could I propose this as a standard to communicate with?

I originally did both hot twist tests and cold twist tests, but now I usually just do the cold twist test, which seems to tell us the most. I forge the bloom to a bar approximately 5/16 inch ( 8 mm) square, (with no folding). Let it air cool. I mark off 1.5 inches ( 38 or 40 mm), and twist it until it breaks, counting the quarter turns.
Close up of twist test
 My low-carbon, high phosphorus blooms break at zero to 1/2 twist, with a crystalline fracture. The low-C, low P blooms go 3/4 to 2 twists- the best we've done so far did 2 full twists, the one shown in the photos.
Ductile fracture at 2 complete twist.
Crystalline fracture at 1/4 twist.
 The hot twist tests I do by forging to 5/8 inch square, marking off 3 inches. heating to yellow. and twisting to failure. The higher P ones actually tend to twist farther hot than the low P ones. Usually in the neighborhood of 3 to 4 twists before it breaks.
I actually have never done this with high C bloom, so I don't know how it acts.

I think this is a great way to judge your iron in your own shop.

The images and text above all by Lee Sauder

 

February 15 - May 15, 2012 : Supported by a Crafts Projects - Creation and Development Grant

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